CONFORMATION AND OPTICAL-ABSORPTION PROPERTIES OF THIOPHENE OLIGOMERS - C-13-NMR, UV, AND MMP2 CALCULATIONS OF DI-QUATERTHIOPHENES AND TETRAMETHYL-QUATERTHIOPHENES

被引：37

作者：

BARBARELLA, G ^{[1
]}

BONGINI, A ^{[1
]}

ZAMBIANCHI, M ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40127 BOLOGNA,ITALY

来源：

ADVANCED MATERIALS | 1991年 / 3卷 / 10期

关键词：

D O I：

10.1002/adma.19910031008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: A combined calculational and experimental study of methylated oligothiophenes allows the effects of different substitution patterns on the geometry, the inter-ring twist, and the conformational and optical properties of the oligomers, which have potential applications in molecular electronics and can be polymerized to polythiophenes, to be examined.

引用

页码：494 / 496

页数：3

共 23 条

[1] ELECTRON DIFFRACTION STUDIES OF 2,2'-DITHIENYL VAPOUR [J].

ALMENNINGEN, A ;

BASTIANSEN, O ;

SVENDSAS, P .

ACTA CHEMICA SCANDINAVICA, 1958, 12 (08) :1671-1674

[2] ORGANIC POLYMERS BASED ON AROMATIC RINGS (POLYPARAPHENYLENE, POLYPYRROLE, POLYTHIOPHENE) - EVOLUTION OF THE ELECTRONIC-PROPERTIES AS A FUNCTION OF THE TORSION ANGLE BETWEEN ADJACENT RINGS [J].

BREDAS, JL ;

STREET, GB ;

THEMANS, B ;

ANDRE, JM .

JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (03) :1323-1329

[3] NEMATIC PHASE NUCLEAR MAGNETIC-RESONANCE INVESTIGATIONS OF ROTATIONAL-ISOMERISM .3. CONFORMATIONAL PREFERENCES AND INTERCONVERSION BARRIER OF 2,2'-BITHIENYL [J].

BUCCI, P ;

LONGERI, M ;

VERACINI, CA ;

LUNAZZI, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (05) :1305-1309

[4] ANALYSIS OF THE CARBON AND PROTON NMR-SPECTRA OF 2-ARYLTHIOPHENES AND RELATED HETEROCYCLES [J].

DELMAZZA, D ;

REINECKE, MG ;

SMITH, WB .

MAGNETIC RESONANCE IN CHEMISTRY, 1989, 27 (02) :187-190

[5]

FICHOU D, 1989, SYNTHETIC MET, V28, pC723, DOI 10.1016/0379-6779(89)90596-1

[6] AN ALL-ORGANIC SOFT THIN-FILM TRANSISTOR WITH VERY HIGH CARRIER MOBILITY [J].

GARNIER, F ;

HOROWITZ, G ;

PENG, XH ;

FICHOU, D .

ADVANCED MATERIALS, 1990, 2 (12) :592-594

[7]

GARNIER F, 1989, SYNTHETIC MET, V28, pC705, DOI 10.1016/0379-6779(89)90594-8

[8]

GARNIER F, 1989, ADV MATER, V1, P117

[9] STERIC EFFECTS ON THE CONTROLLED POTENTIAL ELECTRO-OXIDATION OF 3-METHYLTHIOPHENE AND THIOPHENE OLIGOMERS AND THE PROPERTIES OF THEIR POLYMER-FILMS [J].

LAGURENDAVIDSON, L ;

PHAM, CV ;

ZIMMER, H ;

MARK, HB ;

ONDRUS, DJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (06) :1406-1414

[10] DIPOLE MOMENT AND STRUCTURE OF THIOPHENE DERIVATIVES AND BENZENE ANALOGS [J].

LIEN, EJ ;

KUMLER, WD .

JOURNAL OF PHARMACEUTICAL SCIENCES, 1970, 59 (11) :1685-&

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