Bisdiselenolate metal complexes. Synthesis, structure and electrochemical properties

被引：3
|
作者：
Liu, SG
Liu, YQ
Yang, XY
Zhu, DB
机构：
[1] Institute of Chemistry, Academia Sinica, Beijing 100080, Peoples
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1995年 / 105卷 / 1-4期
关键词：
multi-selenium donor ligand; transition metal complex; crystal structure; electrochemical properties; synthetic metals;
D O I：
10.1080/10426509508042050
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The multi-selenium donor ligand 2,2-dicyanoethylene-1,1-diselenolate (DCNSe) has been prepared. The dianionic complex of DCNSe with Ni(II) has been isolated as the tetrabutylammonium (TEA) salt. The compound is characterized by negative ion Fast Atom Bombardment (FAB) mass spectral analysis, Fourier Transform Infrared (FT-IR) spectral analysis, UV-Vis spectral analysis and cyclic voltammetry. The electrochemical properties and crystal structure are studied as well. In addition, the corresponding Cu(II) complex has been isolated as the TEA salt and characterized by negative ion FAB mass spectral analysis and FT-IR spectral analysis.
引用
收藏
页码：83 / 91
页数：9
相关论文
共 50 条
  • [41] Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes
    Hu, Kong-Qiu
    Wu, Shu-Qi
    Cui, Ai-Li
    Kou, Hui-Zhong
    TRANSITION METAL CHEMISTRY, 2014, 39 (06) : 713 - 718
  • [42] Complexes of silanethiolate ligands: Synthesis, structure, properties and application
    Pladzyk, Agnieszka
    Kowalkowska-Zedler, Daria
    Ciborska, Anna
    Schnepf, Andreas
    Dolega, Anna
    COORDINATION CHEMISTRY REVIEWS, 2021, 437
  • [43] Synthesis and electrochemical properties of pentacarbonylchromium and tungsten complexes containing pyrazole ligands
    Jia, WL
    Tang, LF
    Chai, JF
    Wang, ZH
    Wang, JT
    ACTA CHIMICA SINICA, 2001, 59 (02) : 201 - 206
  • [44] Synthesis, photophysical and electrochemical properties of aza-boron-diquinomethene complexes
    Wang, Danfeng
    Liu, Rui
    Chen, Chen
    Wang, Shifan
    Chang, Jin
    Wu, Chunhui
    Zhu, Hongjun
    Waclawik, Eric R.
    DYES AND PIGMENTS, 2013, 99 (01) : 240 - 249
  • [45] Thiodiacetate cobalt(II) complexes: Synthesis, structure and properties
    Grirrane, A
    Pastor, A
    Alvarez, E
    Mealli, C
    Ienco, A
    Masi, D
    Galindo, A
    INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (05) : 463 - 466
  • [46] Synthesis and electrochemical properties of NiO nanospindles
    Zhou, Hai
    Lv, Baoliang
    Xu, Yao
    Wu, Dong
    MATERIALS RESEARCH BULLETIN, 2014, 50 : 399 - 404
  • [47] Metal Cyanamides/Carbodiimides: Structure, Synthesis and Electrochemical Energy Storage Performance
    Zhao Wei
    Xu Yang
    Wan Yingjie
    Cai Tianxun
    Mu Jinxiao
    Huang Fuqiang
    JOURNAL OF INORGANIC MATERIALS, 2022, 37 (02) : 140 - 151
  • [48] Synthesis, crystal structure, Hirshfeld surface analysis and characterization of two new mononuclear Ni(II) complexes.
    Mandal, Uttam
    Rizzoli, Corrado
    Chakraborty, Bikash
    Bandyopadhyay, Debasis
    Mandal, Santanu
    JOURNAL OF MOLECULAR STRUCTURE, 2024, 1302
  • [49] Synthesis, Structural Characterization,and Electrochemical Properties of Binuclear Copper(Ⅱ) Complexes Containing Tetradentate Schiff Base Ligand
    DING Yu
    Wuhan University Journal of Natural Sciences, 2010, 15 (02) : 165 - 170
  • [50] Brominated boron dipyrrins: synthesis, structure, spectral and electrochemical properties
    Lakshmi, V.
    Ravikanth, M.
    DALTON TRANSACTIONS, 2012, 41 (19) : 5903 - 5911
12345