SYNTHESIS AND CRYSTAL-STRUCTURE OF THE SELENYL-PHOSPHORANEIMINATO COMPLEX SEO(NPPH(3))(2)

被引：4
|
作者：
FOLKERTS, H
DEHNICKE, K
MAICHLEMOSSMER, C
STRAHLE, J
机构：
[1] UNIV MARBURG,FACHBEREICH CHEM,W-3550 MARBURG,GERMANY
[2] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 07期
关键词：
SELENIUM; PHOSPHORANE IMINATO COMPLEX OF SELENIUM; SYNTHESIS; IR SPECTRUM; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19956210709
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
SeO(NPPh(3))(2) has been prepared from SeO2 and Me(3)SiNPPh(3) in a SeO2 suspension in acetonitrile, forming colourless crystals. The compound is characterized by IR spectrescopy and by a crystal structure determination. Space group P $($) over bar$$ 1, Z = 2, structure solution with 5344 observed unique reflections, R = 0.064. Lattice dimensions at -40 degrees C: a = 931.6,b = 947.6, c = 1762 pm, alpha = 77.50 degrees, beta = 81.78 degrees, gamma = 79.23 degrees. The compound forms monomeric molecules in which the selenium atom is phi-tetrahedrally surrounded with bond lengths SeO = 161.7 pm and SeN = 179.9 and 181.6 pm.
引用
收藏
页码：1171 / 1174
页数：4
相关论文
共 50 条
  • [41] Synthesis, Crystal Structure and Nonlinear Optical Property of K2W3SeO12
    Huang Yin
    Meng Xiang-Gao
    Qin Jin-Gui
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (01) : 179 - 184
  • [42] CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF SOPHIITE, ZN2(SEO3)CL2, A NEW MINERAL
    SEMENOVA, TF
    ROZHDESTVENSKAYA, IV
    FILATOV, SK
    VERGASOVA, LP
    MINERALOGICAL MAGAZINE, 1992, 56 (383) : 241 - 245
  • [43] SYNTHESIS AND CRYSTAL-STRUCTURE OF [LICL.2THF]2
    HAHN, FE
    RUPPRECHT, S
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (02): : 143 - 146
  • [44] SYNTHESIS AND CRYSTAL-STRUCTURE DETERMINATION OF LIAL[(P2O6)2]
    BRUHNE, B
    JANSEN, M
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (08): : 1409 - 1412
  • [45] SYNTHESIS AND CRYSTAL-STRUCTURE OF [(ME3SI)2CH(I-PR)INCL]2
    NEUMULLER, B
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (11): : 1539 - 1543
  • [46] Synthesis and Crystal Structure of Pb4(V3O8)2(SeO3)3
    Kovrugin, Vadim M.
    Colmont, Marie
    Mentre, Olivier
    Siidra, Oleg I.
    Krivovichev, Sergey V.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2013, 69 : S463 - S463
  • [47] SYNTHESIS AND CRYSTAL-STRUCTURE OF (PPH4)2TE4
    WOLKERS, H
    SCHREINER, B
    STAFFEL, R
    MULLER, U
    DEHNICKE, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (08): : 1015 - 1019
  • [48] Synthesis and Crystal Structure of a new Cu2+ complex
    Xu Huo-Ying
    Jiang Yin-Zhi
    Zou Yang
    Zhang Lian-Qun
    FRONTIERS OF MATERIALS, CHEMICAL AND METALLURGICAL TECHNOLOGIES, PTS 1 AND 2, 2012, 581-582 : 193 - 196
  • [49] SYNTHESIS AND CRYSTAL-STRUCTURE OF [((CO)5CRPHP)2SE3]
    MERZWEILER, K
    KERSTEN, HJ
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1992, 47 (11): : 1649 - 1651
  • [50] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DICHLORO-SELENONITRENE COMPLEX (PPH4)2[WCL5(NSECL2)]
    VOGLER, S
    DEHNICKE, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1992, 47 (03): : 301 - 304
12345