rac-2-Phenyl-1-[(2,4,6-triisopropyl-benzene)sulfonyl]aziridine

被引：2

作者：

Golz, Christopher ^{[1
]}

Preut, Hans ^{[1
]}

Strohmann, Carsten ^{[1
]}

机构：

[1] Tech Univ Dortmund, Fak Biol Chem & Chem Biol, Otto Hahn Str 6, D-44221 Dortmund, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

data-to-parameter ratio = 17.3; mean σ(C-C) = 0.003 Å; R factor = 0.042; single-crystal X-ray study; T = 173 K; wR factor = 0.107;

D O I：

10.1107/S1600536814000257

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C23H31NO2S, the geometry of the triisopropylphenyl group is slightly distorted, with elongated C-C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228 (2) angstrom. This distortion is caused by the bulky substituents and, in comparison, an unbent geometry is observed in N-toluenesulfonylaziridine [Zhu et al. (2006). Acta Cryst. E62, o1507-o1508]. pi-pi interactions between adjacent benzene rings [centroidcentroid distance = 3.7928 (11) angstrom] and are observed.

引用

页码：0153 / +

页数：9

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