COMPLEXES OF IN(III) WITH TETRAPHENYLIMIDODIPHOSPHINATE LIGANDS

被引：18

作者：

CEAOLIVARES, R

TOSCANO, RA

CARREON, G

VALDESMARTINEZ, J

机构：

[1] Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, 04510, D. F.

来源：

MONATSHEFTE FUR CHEMIE | 1992年 / 123卷 / 05期

关键词：

INDIUM COMPLEXES; TETRAPHENYLIMIDODIPHOSPHINATES; INORGANIC RINGS; WYNNE THEORY;

D O I：

10.1007/BF00817594

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis and characterization of the inorganic heterocyclic complexes In(OPPh2NPPh2O)3 and In(SPPh2NPPh2S)3. The structure of the sulfur derivative was determined by X-ray methods. The complex presents a distorted Oh symmetry and it is compared with the Bi(III) analog. The P-31-NMR data and the X-ray structural determination suggest that the bulky ligands are responsible for the geometrical features in these complexes and therefore, for the Bi(III) analogs perhaps the lone pair does not play an important role in the structure.

引用

页码：391 / 396

页数：6

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