POLYAZOLYL CHELATE CHEMISTRY .4. DIHYDROBIS(BENZOTRIAZOLYL)BORATO COMPLEXES OF RUTHENIUM(II)

被引：25

作者：

CARTWRIGHT, J ^{[1
]}

HILL, AF ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 429卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83253-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the salt K[H2B(bta)2] (bta = benzotriazol-1-yl) with the compounds [RuClR(CO)-(PPh3)n] (n = 3, R = H; n = 2, R = C6H4Me-4. CH=CHC6H4Me-4, CH=CHC4H9, C(C=CPh)=CHPh) give high yields of the chelate complexes [RuR(CO)(PPh3)2{eta-2-H2B(bta)2}]. The hydrido complex can also be made by similar treatment of the salt [RuH(NCMe)2(CO)(PPh3)2]BF4, and gives the chloro-derivative [RuCl(CO)(PPh3)2{eta-2-H2B(bta)2}] upon treatment with N-chlorosuccinimide.

引用

页码：229 / 238

页数：10

共 25 条

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