MODEL FOR ETHYLENE-ALPHA-OLEFIN COPOLYMERIZATION

被引：13
|
作者：
LORENZINI, P
BERTRAND, P
VILLERMAUX, J
机构：
[1] SOC FRANCAISE POLYETHYLENE,GRP ENIMONT,F-62670 MAZINGARBE,FRANCE
[2] SOC FRANCAISE POLYETHYLENE,GRP ENIMONT,F-92411 COURBEVOIE,FRANCE
来源：
CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 1991年 / 69卷 / 03期
关键词：
D O I：
10.1002/cjce.5450690310
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A copolymerization model of ethylene and a alpha-olefin describing the monomer uptake and the quality of the polymer produced, namely M(n), M(w), M(z), the distribution of molecular weight, short branching index and double bonds, is presented. This model assumes the existence of several types of active sites (2 or 3) and do not involve any limiting diffusion. It is applied to ethylene and butene-1 bulk copolymerization at high pressure and high temperature. Parameters are identified with CSTR experiments.
引用
收藏
页码：682 / 697
页数：16
相关论文
共 50 条
  • [1] ON THE ISOMORPHISM OF ETHYLENE-ALPHA-OLEFIN COPOLYMERS
    SEGUELA, R
    RIETSCH, F
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1986, 24 (01) : 29 - 33
  • [2] Mechanical properties of ethylene-alpha-olefin copolymers
    Fatou, JG
    Macia, IG
    Marco, C
    Gomez, MA
    Arribas, JM
    Fontecha, A
    Aroca, M
    Martinez, MC
    JOURNAL OF MATERIALS SCIENCE, 1996, 31 (12) : 3095 - 3107
  • [3] EFFECT OF CHAIN MICROSTRUCTURE ON MODULUS OF ETHYLENE-ALPHA-OLEFIN COPOLYMERS
    SEHANOBISH, K
    PATEL, RM
    CROFT, BA
    CHUM, SP
    KAO, CI
    JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 51 (05) : 887 - 894
  • [4] Compatibility of binary blends of polypropylene with ethylene-alpha-olefin copolymer
    Yamaguchi, M
    Miyata, H
    Nitta, KH
    JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 62 (01) : 87 - 97
  • [5] Effect of aging on film properties of ethylene-alpha-olefin copolymers
    Mavridis, H
    JOURNAL OF PLASTIC FILM & SHEETING, 2002, 18 (04) : 259 - 268
  • [6] Dynamic rheological properties of HDPE/ethylene-alpha-olefin copolymer blends
    Morales, RA
    Sánchez, JJ
    Müller, AJ
    ANTEC 2000: SOCIETY OF PLASTICS ENGINEERS TECHNICAL PAPERS, CONFERENCE PROCEEDINGS, VOLS I-III, 2000, : 3654 - 3654
  • [7] READILY CURABLE CHLORINATED POLY-ALPHA-OLEFINS + ETHYLENE-ALPHA-OLEFIN COPOLYMERS
    MAKOWSKI, HS
    WEI, PE
    CAIN, WP
    INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1964, 3 (04): : 282 - &
  • [8] Mechanical properties of binary blends of polypropylene with ethylene-alpha-olefin copolymer
    Nitta, K
    Okamoto, K
    Yamaguchi, M
    POLYMER, 1998, 39 (01) : 53 - 58
  • [9] INFRARED DICHROISM OF THE METHYL-GROUP FOR SOME ETHYLENE-ALPHA-OLEFIN COPOLYMERS
    HOSODA, S
    FURUTA, M
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1981, 2 (9-10): : 577 - 583
  • [10] FEATURES OF THE STRUCTURE OF RELAXATORS OF ETHYLENE-ALPHA-OLEFIN COPOLYMERS IN THE LOW-TEMPERATURES REGION
    ALIGULIEV, RM
    KHITEEVA, DM
    IBRAGIMOV, KD
    OGANYAN, VA
    NURIEV, RA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1989, 31 (12): : 907 - 911
12345