UNIFIED LATTICE THEORY OF HOMOPOLYMERS OF GENERAL ARCHITECTURE - DENDRIMERS, STARS, AND BRANCHED POLYMERS

被引:33
作者
GUJRATI, PD [1 ]
机构
[1] UNIV AKRON,DEPT POLYMER SCI,AKRON,OH 44325
关键词
D O I
10.1103/PhysRevLett.74.1367
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present a lattice theory of homopolymers of a variety of architectures. The effective has a strong concentration dependence, and at the point is (q/2)ln(q-1)/(q-2) for all architectures, where q is the coordination of the lattice. We give the closed-form expressions for the entropy, the free energy, and the complete phase diagram. The latter is restricted to systems having no first-order transitions in athermal solutions. © 1995 The American Physical Society.
引用
收藏
页码:1367 / 1370
页数:4
相关论文
共 13 条
[1]  
[Anonymous], 1979, SCALING CONCEPTS POL
[2]   POLYMERIZATION IN MICROEMULSIONS WITH METALLOSURFACTANTS [J].
ANTONIETTI, M ;
NESTL, T .
MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (02) :111-116
[3]  
BEACHAOUCH S, 1994, MACROMOL RAPID COMM, V15, P125
[4]  
FLORY PJ, 1959, PRINCIPLES POLYM CHE
[5]   DENDRIMERS AS MACROINITIATORS FOR ANIONIC RING-OPENING POLYMERIZATION - POLYMERIZATION OF EPSILON-CAPROLACTONE [J].
GITSOV, I ;
IVANOVA, PT ;
FRECHET, JMJ .
MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (05) :387-393
[6]   ORDERING FIELD, ORDER PARAMETER, AND SELF-AVOIDING WALKS [J].
GUJRATI, PD .
PHYSICAL REVIEW LETTERS, 1984, 53 (26) :2453-2456
[8]  
GUJRATI PD, UNPUB
[9]  
GUJRATI PD, IN PRESS PHYS REV E
[10]  
HALPERIN A, 1990, ADV POLYM SCI, V100, P31