A DIRECT SYNTHESIS OF OLEFINS BY REACTION OF CARBONYL-COMPOUNDS WITH LITHIO DERIVATIVES OF 2-[ALKYL-SULFONYL OR (2'-ALKENYL)-SULFONYL OR BENZYL-SULFONYL]-BENZOTHIAZOLES

被引：370

作者：

BAUDIN, JB ^{[1
]}

HAREAU, G ^{[1
]}

JULIA, SA ^{[1
]}

RUEL, O ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,CHIM LAB,24 RUE LHOMOND,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)92037-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

During the title reaction, the lithium alkoxides formed as intermediates undergo an intramolecular addition to the neighboring C = N group followed an S to 0 benzothiazole transfer and simultaneous extrusion of sulfur dioxide and ejection of 2(3H)-benzothiazolone anion.

引用

页码：1175 / 1178

页数：4

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