DESIGN OF A DIFFERENTIAL PRESSURE CELL, VLE OF ALDEHYDE SYSTEMS AND NEW UNIFAC PARAMETERS

被引：9

作者：

KASSMANN, KD

KNAPP, H

机构：

[1] Technical Univ of Berlin, Berlin, West Ger, Technical Univ of Berlin, Berlin, West Ger

来源：

FLUID PHASE EQUILIBRIA | 1986年 / 29卷

关键词：

ALDEHYDES - Vapor Pressure - AROMATIC COMPOUNDS - EQUATIONS OF STATE - MIXTURES;

D O I：

10.1016/0378-3812(86)85025-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A great variety of equipment has been designed for the investigation of low pressure vapor-liquid equilibria. Each specific apparatus has advantages and disadvantages depending on the operating conditions and on the properties of the substances. Measurements in the state of high dilution can be made either by measuring the differential temperature between two isobarically operated ebulliometers or by measuring the differential pressure between two isothermally operated static cells. The latter method is preferable if a high volatile component is added to a low volatile solvent. A thermostated dynamic VLE-apparatus and a recently designed differential pressure static double cell apparatus will be described, operating experience will be reported and experimental results will be presented and discussed.

引用

页码：241 / 248

页数：8