CONSTITUTION OF THE HF-NI SYSTEM UP TO 50 AT-PERCENT NI

被引:16
作者
YEREMENKO, VN
SEMENOVA, EL
TRETYACHENKO, LA
PETYUKH, VM
机构
[1] I.N. Frantsevich Institute for Problems of Material Science, Academy of Science of Ukraine, Kiev
关键词
Crystal structure - Eutectics - Hafnium alloys - Melting - Nickel alloys - Phase diagrams - Phase transitions;
D O I
10.1016/0925-8388(93)90281-Q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Hf-Ni system phase diagram has been reinvestigated in the hafnium-rich composition range up to 50 at.% Ni. Two intermetallic compounds Hf2Ni and HfNi melting congruently at 1220-degrees-C and 1505-degrees-C, respectively, were observed. There are two eutectics: L half arrow right over half arrow left beta-Hf + Hf2Ni with about 29 at.% Ni at 1145-degrees-C and L reversible Hf2Ni + HfNi with about 35 at.% Ni at 1175-degrees-C. Allotropic transformation in HfNi takes place at 1150-degrees-C. The cubic CsCl-type crystal structure of the high temperature modification of HfNi has been determined indirectly for the first time.
引用
收藏
页码:117 / 119
页数:3
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