ELECTRONIC LEVEL STRUCTURE OF GROUP-III HEAVY ELEMENT CLUSTERS STUDIED BY PHOTOELECTRON-SPECTROSCOPY

被引：25

作者：

GAUSA, M

GANTEFOR, G

LUTZ, HO

MEIWESBROER, KH

机构：

[1] Fakultät für Physik, Universität Bielefeld

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 1990年 / 102卷

关键词：

D O I：

10.1016/0168-1176(90)80062-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

UV-photoelectrons of mass-defined indium and thallium cluster anions have been analyzed at a detachment energy of 3.68 eV in the size range n = 2-20. The photoelectron threshold energies are in rough agreement with the values predicted by the metal droplet model. A number of low-lying excited states of the neutral-clusters are detected. The high atomic s-orbital binding energies appear to induce alkali-like character of In(n)- and Tl(n)-.

引用

页码：227 / 237

页数：11

共 31 条

[1] THEORETICAL-STUDY OF THE STABILITY OF AG-N(2+), AG-N(+), AG-N, AG-N(-) AND NA-N(-) CLUSTERS AS A FUNCTION OF SIZE USING THE DENSITY FUNCTIONAL FORMALISM [J].