ENZYMATIC-SYNTHESIS OF POLYPHENOLS AND THEIR THERMAL-PROPERTIES

被引：8
作者：
UYAMA, H
KURIOKA, H
KOMATSU, I
SUGIHARA, J
KOBAYASHI, S
机构：
[1] Department of Molecular Chemistry and Engineering, Faculty of Engineering, Tohoku University, Aoba
来源：
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1995年 / A32卷
关键词：
D O I：
10.1080/10601329508018954
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Enzymatic oxidative polymerization of phenol and its derivatives was carried out in a mixture of 1,4-dioxane and buffer using peroxidase as catalyst to produce a new family of polyphenols. The monomers used in this study were phenol and p-n-alkylphenols. The polymer obtained from phenol by the use of horseradish peroxidase as catalyst was partly soluble in DMF and DMSO, and the molecular weight of the soluble part was determined by GPC as around 3x10(4). The polymer was found to possess highly thermal stability from TG analysis.
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页码：649 / 654
页数：6
相关论文
共 12 条
[1]   SYNTHESIS AND CHARACTERIZATION OF POLYMERS PRODUCED BY HORSERADISH-PEROXIDASE IN DIOXANE [J].
AKKARA, JA ;
SENECAL, KJ ;
KAPLAN, DL .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (11) :1561-1574
[2]   POLYMERIZATION OF PHENOLS CATALYZED BY PEROXIDASE IN NONAQUEOUS MEDIA [J].
DORDICK, JS ;
MARLETTA, MA ;
KLIBANOV, AM .
BIOTECHNOLOGY AND BIOENGINEERING, 1987, 30 (01) :31-36
[3]   NOVEL METHOD FOR POLYSACCHARIDE SYNTHESIS USING AN ENZYME - THE 1ST INVITRO SYNTHESIS OF CELLULOSE VIA A NONBIOSYNTHETIC PATH UTILIZING CELLULASE AS CATALYST [J].
KOBAYASHI, S ;
KASHIWA, K ;
KAWASAKI, T ;
SHODA, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3079-3084
[4]   ENZYMATIC OXIDATION POLYMERIZATION OF ORTHO-PHENYLENEDIAMINE [J].
KOBAYASHI, S ;
KANEKO, I ;
UYAMA, H .
CHEMISTRY LETTERS, 1992, (03) :393-394
[5]  
KOBAYASHI S, 1993, MAKROMOL CHEM-RAPID, V14, P841
[6]  
KOBAYASHI S, IN PRESS ADV POLYM S
[7]   ENZYMATIC OXIDATIVE POLYMERIZATION OF ALKYLPHENOLS [J].
KURIOKA, H ;
KOMATSU, I ;
UYAMA, H ;
KOBAYASHI, S .
MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (06) :507-510
[8]  
RITTER H, 1993, TRENDS POLYM SCI, V1, P173
[9]   SYNTHESIS OF A NEW FAMILY OF PHENOL RESIN BY ENZYMATIC OXIDATIVE POLYMERIZATION [J].
UYAMA, H ;
KURIOKA, H ;
KANEKO, I ;
KOBAYASHI, S .
CHEMISTRY LETTERS, 1994, (03) :423-426
[10]   ENZYMATIC RING-OPENING POLYMERIZATION OF LACTONES CATALYZED BY LIPASE [J].
UYAMA, H ;
KOBAYASHI, S .
CHEMISTRY LETTERS, 1993, (07) :1149-1150
12