MECHANISM AND DYNAMICS OF ION TRANSFER ACROSS A LIQUID-LIQUID INTERFACE

被引：208
|
作者：
BENJAMIN, I
机构：
[1] Department of Chemistry, University of California, Santa Cruz
来源：
SCIENCE | 1993年 / 261卷 / 5128期
关键词：
D O I：
10.1126/science.261.5128.1558
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
A detailed molecular model for ion transfer across the interface between water and 1,2-dichloroethane provides insight into the mechanism of the transfer across the interface between two immiscible liquids Extensive molecular dynamics computer simulations underscore the roles of surface roughness and capillary distortions in this process, demonstrate that ion transfer is an activated rather than a simple diffusive process, and provide a test for the applicability of theoretical models.
引用
收藏
页码：1558 / 1560
页数：3
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