STEREOCHEMISTRY OF ASYMMETRIC SILICON .15. STEREOSPECIFIC HYDROSILATION AND EXCHANGE REACTIONS OF R3SI]H(D) CATALYZED BY GROUP 8 METAL CENTERS

被引：101

作者：

SOMMER, LH

LYONS, JE

FUJIMOTO, H

机构：

[1] Department of Chemistry, University of California, Davis

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 25期

关键词：

D O I：

10.1021/ja01053a027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of R3Si*H to olefins (hydrosilation) catalyzed by transition metal centers proceeds with retention of configuration as do Si*H-Si*D isotopic-exchange reactions. The data are accommodated by the general mechanistic conclusion that the initial process in these reactions involves stereospecific retentive interaction of the Si*-H bond with the reactive transition metal center to form a metal-silicon bond which then reacts in a variety of ways with complete retention of configuration in hydrosilation and isotopic exchange reactions. © 1969, American Chemical Society. All rights reserved.

引用

页码：7051 / &

共 38 条

[1]

AYLETT BJ, 1967, CHEM COMMUN, P159

[2] THE STEREOCHEMISTRY OF THE ADDITION OF SILICOCHLOROFORM TO ACETYLENES [J].