ALDOL REACTIONS OF ALPHA-(N,N-DIBENZYLAMINO) ETHYL KETONES

被引：19

作者：

GOH, JB ^{[1
]}

LAGU, BR ^{[1
]}

WURSTER, J ^{[1
]}

LIOTTA, DC ^{[1
]}

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 33期

关键词：

D O I：

10.1016/0040-4039(94)88066-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aldol reactions of the sodium enolates of alpha-(N,N-dibenzylamino) ethyl ketones proceed in a highly diastereoselective fashion and result in the formation of the all syn adduct. The observed stereoselectivities are most easily understood in the context of an open transition state.

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页码：6029 / 6032

页数：4

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