IMINO-ETHER COMPLEXES OF PLATINUM - CIS-[PTCL2(NH=C(OR)ME)2] AND [PTCL4(NH=C(OR)ME)2], WHERE R = ME, ET AND PR-ISO - PREPARATION, CHARACTERIZATION AND X-RAY STRUCTURE FOR [PTCL2(NH=C(OPR-ISO)ME)2]2

被引：29

作者：

CASAS, JM

CHISHOLM, MH

SICILIA, MV

STREIB, WE

机构：

[1] INDIANA UNIV, DEPT CHEM, BLOOMINGTON, IN 47405 USA

[2] INDIANA UNIV, CTR MOLEC STRUCT, BLOOMINGTON, IN 47405 USA

来源：

POLYHEDRON | 1991年 / 10卷 / 13期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86083-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of cis-PtCl2(NCMe)2 with KOH or KOPh in MeOH, EtOH or Pr(i)OH produces the imino-ether complexes [PtCl2(NH = C(OR)Me)2] which have been characterized by IR, NMR and elemental analysis. The crystal structure of [PtCl2(NH = C(OPr(i))Me)2]2 was determined by X-ray diffraction. Each molecule comprises two units of [PtCl2(NH = C(OPr(i))Me)2] with a Pt---Pt distance of 3.327(1) angstrom. The lack of any bridging ligand suggests the presence of hydrogen bonds. The N(4)-Cl(3') and N(11)-Cl(2') distances are within the range of van der Waals' interactions. Oxidation reactions of these compounds with C6H5ICl2 give the corresponding platinum(IV) complexes [PtCl4(NH = C(OR)Me)2].

引用

页码：1573 / 1578

页数：6

共 27 条

[1] HALOGEN OXIDATION OF TETRAKIS(DITHIOACETATO)DIPLATINUM(II) COMPLEXES, PT2(CH3CS2)4 - SYNTHESIS AND CHARACTERIZATION OF PT2(CH3CS2)4X2 (X = CL, BR, I) AND STRUCTURAL, ELECTRICAL, AND OPTICAL-PROPERTIES OF LINEAR-CHAIN (MU-IODO)TETRAKIS(DITHIOACETATO)DIPLATINUM, PT2(CH3CS2)4I [J].