SEPARATION OF SR-89 AND SR-90 FROM CALCIUM IN MILK WITH A MACROCYCLIC ETHER

被引:51
作者
KIMURA, T
IWASHIMA, K
ISHIMORI, T
HAMADA, T
机构
[1] INST PUBL HLTH,DEPT RADIOL HLTH,MINATO KU,TOKYO 108,JAPAN
[2] RIKKYO UNIV,INST ATOM ENERGY,YOKOSUKA,KANAGAWA 42001,JAPAN
[3] INST PHYS & CHEM RES,WAKO,SAITAMA 351,JAPAN
关键词
D O I
10.1021/ac50044a005
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A small amount of strontium ion (20 mg) was simply separated from a large amount of calcium ion (0.5-13.6 g) by liquid-liquid extraction using dicyclohexyl 18-crown-6 chloroform solution. The extraction was applied to a part of the procedure for determining radiostrontium in ash of milk. The overall recovery of strontium was 75% on the average for 5-10 g of milk ash. Decontamination factors for Mg, Ca, Ru, I, Cs, Ba, and La in the final fraction were 1 × 105, 1 × 104, >1 × 106, >1 × 106, >2 × 106, 2 × 105, and 3 × 104, respectively. The chemical procedure for three samples took about 2 days. © 1979, American Chemical Society. All rights reserved.
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页码:1113 / 1116
页数:4
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