ORGANOSILVER COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF THE YLIDE DISILVER COMPLEX [AGCH2P(S)PH2]2

被引：31

作者：

WANG, SN

FACKLER, JP

CARLSON, TF

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843

[2] TEXAS A&M UNIV SYST,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1021/om00156a045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Summary: A dimeric silver(I) complex, [Ag(CH2PPh2S)]2(1), was obtained by the reaction of Li(CH2PPh2S) with AgNO3 in THF solution at -78 °C. The X-ray crystal structure of 1 shows that the ylide ligand CH2PPh2S bridges two Ag1 atoms with a Ag’-Ag1 separation of 2.990 (2) A. 1 has a one-dimensional chain structure in the solid with an intermolecular Ag-Ag separation of 3.227 (2) Λ. © 1990, American Chemical Society. All rights reserved.

引用

页码：1973 / 1975

页数：3

共 25 条

[1] EXPERIMENTAL AND THEORETICAL-STUDIES OF DINUCLEAR GOLD(I) AND GOLD(II) PHOSPHORUS YLIDE COMPLEXES - OXIDATIVE ADDITION, HALIDE EXCHANGE, AND STRUCTURAL-PROPERTIES INCLUDING THE CRYSTAL AND MOLECULAR-STRUCTURES OF [AU(CH2)2PPH2]2 AND [AU(CH2)2PPH2]2(CH3)BRI [J].