NEW COMPOUNDS K2-XV8016, TL2-XV8016 WITH HOLLANDITE TYPE STRUCTURE

被引：50
作者：
ABRIEL, W
RAU, F
RANGE, KJ
机构：
[1] Institut für Chemie der Universität Regensburg, D-8400 Regensburg
来源：
MATERIALS RESEARCH BULLETIN | 1979年 / 14卷 / 11期
关键词：
D O I：
10.1016/0025-5408(79)90090-4
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
K2V8O16, K1.8V8O16 and Tl1.74V8O16 were synthesized by high pressure- high temperature treatment of KVO3 and TlVO3 in a modified Belt-type apparatus. The compounds crystallize tetragonal, space group I4/m. They are the first well-characterized Vanadium-hollandites and show a remarkable high occupation of the tunnel sites with univalent cations. © 1979.
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页码：1463 / 1468
页数：6
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