KINETICS OF LIGAND SUBSTITUTION-REACTIONS - OBSERVATION ON REACTION OF NICKEL(II) TRIETHYLENE TETRAMINE HEXAACETATE WITH CYANIDE ION

被引：5

作者：

KUMAR, K

NIGAM, PC

机构：

[1] Department of Chemistry, Indian Institute of Technology, Kanpur, U.P.

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1979年 / 9卷 / 02期

关键词：

Cyanide kinetics triethylenetetraminehexaacetatonickel. Kinetics cyanide triethylenetetramine-hexacetatonickel; Nickel triethylenetetraminehexaacetate kinetics cyanide; Triethylenetetraminehexaacetatonickel kinetics;

D O I：

10.1080/00958977908076518

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics and mechanism of reaction between NiTTHA (where TTHA = triethylene tetramine hexaacetic acid) and cyanide ion at pH = 10.6; temp = 24°C and ju = 0.1 M studied earlier by Stara and Kopanica has been reinterpieted in the light of investigations of aminocarboxylatonickel(II) reactions with cyanide ion under similar conditions. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：139 / 140

页数：2

共 7 条

[1] KINETICS OF REACTION BETWEEN CYANIDE ION AND NICKEL(II) COMPLEXES OF IMINODIACETATE AND N-METHYLIMINODIACETATE [J].

COOMBS, LC ;

MARGERUM, DW .

INORGANIC CHEMISTRY, 1970, 9 (07) :1711-&

[2] MECHANISM OF TETRACYANONICKELATE FORMATION FROM MONO(AMINOCARBOXYLATE)NICKEL(II) COMPLEXES [J].

COOMBS, LC ;

MARGERUM, DW ;

NIGAM, PC .

INORGANIC CHEMISTRY, 1970, 9 (09) :2081-&

[3] STABILITY CONSTANTS OF SOME METAL CHELATES OF TRIETHYLENETETRAMINEHEXAACETIC ACID (TTHA) [J].

HARJU, L .

ANALYTICA CHIMICA ACTA, 1970, 50 (03) :475-&

[4] KINETICS AND MECHANISM OF TETRACYANONICKELATE FORMATION .1. FROM MONO(AMINOCARBOXYLATE)NICKEL(II) COMPLEXES [J].

KUMAR, K ;

NIGAM, PC ;

PANDEY, GS .

JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (18) :1955-1961

[5]

MARGERUM DW, 1961, J AM CHEM SOC, V83, P1971

[6]

PAGENKOPF GK, 1972, J COORD CHEM, V2, P129

[7] KINETICS OF LIGAND SUBSTITUTION REACTION - NICKEL(II)-TRIETHYLENETETRAMINEHEXAACETATE WITH CYANIDE IONS [J].

STARA, V ;

KOPANICA, M .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1972, 37 (09) :2882-&

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