INTERNAL ROTATION IN PHENYLSILANE AND PHENYLGERMANE AND THEIR -D3 DERIVATIVES

被引：25

作者：

FLEMING, JW

BANWELL, CN

机构：

[1] The Chemical Laboratory, The University, Brighton, Sussex England

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1969年 / 31卷 / 02期

关键词：

D O I：

10.1016/0022-2852(69)90362-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Theory is presented by which the effects of free, or slightly hindered, internal rotation on the infrared spectra of a certain class of molecules may be considered. As examples, calculations based on the theory are compared with observations on the XY3 group vibrations of phenylsilane, phenylgermane, and their -D3 derivatives. Some estimates are given for the heights of the barriers hindering the motion in these molecules. © 1969.

引用

页码：318 / &

共 8 条

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