GLOW DISCHARGE POLYMERIZATION-STYRENE

被引：100

作者：

DENARO, AR

OWENS, PA

CRAWSHAW, A

机构：

[1] Department of Chemistry and Biology, Liverpool Regional College of Technology, Liverpool

来源：

EUROPEAN POLYMER JOURNAL | 1968年 / 4卷 / 01期

关键词：

D O I：

10.1016/0014-3057(68)90010-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The deposition of polymer on the electrodes of a radiofrequency glow discharge through styrene vapour has been investigated. The polymer films have been shown to contain trapped radicals and the rate of deposition of polymer has been examined as a function of pressure and discharge power. The results have been interpreted quantitatively on the basis of a mechanism involving the competitive reactions of radicals formed on the electrodes by electron bombardment. The propagation step is considered to involve the reaction of the radicals with adsorbed monomer and with monomer diffusing to the electrodes from the gas phase.

引用

页码：93 / +

页数：1

共 16 条

[1]

ADAMSON AW, 1960, PHYSICAL CHEMISTRY S, P479

[2] STUDIES IN POLYMERIZATION .9. THE OCCLUSION OF FREE RADICALS BY POLYMERS - PHYSICAL FACTORS DETERMINING THE CONCENTRATION AND BEHAVIOUR OF TRAPPED RADICALS [J].