GROWTH-MECHANISM OF TRANSPARENT AND CONDUCTING COMPOSITE FILMS OF POLYANILINE

被引：9
|
作者：
WAN, MX
YANG, J
机构：
[1] Institute of Chemistry, Academia Sinica, Beijing
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1993年 / 49卷 / 09期
关键词：
D O I：
10.1002/app.1993.070490916
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Composites of polyaniline (PANI) with various polymeric matrices as substrates were synthesized by means of diffusion-oxidation of aniline swollen polymeric matrices with FeCl3 as oxidizer. The conductivity at room temperature, transmittance at 400-800 nm, stability in air, and morphology of PANI composite films depend on the polymerization time, concentration of FeCl3, and substrate used. A maximum conductivity at room temperature and the highest transmittance at 500-800 nm can be achieved of 10(-1) S/cm and 70-80%, respectively. The growth mechanism of PANI composite films has been discussed. (C) 1993 John Wiley & Sons, Inc.
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收藏
页码：1639 / 1645
页数：7
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