2,2-DIFLUORO ENOL SILYL ETHERS - CONVENIENT PREPARATION AND APPLICATION TO THE SYNTHESIS OF A NOVEL FLUORINATED BRASSINOSTEROID

被引：52
|
作者：
JIN, FQ [1 ]
XU, YY [1 ]
HUANG, WY [1 ]
机构：
[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 07期
关键词：
D O I：
10.1039/p19930000795
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
on treatment with Grignard reagents, trifluoroacetyltriphenylsilane was converted into 2,2-difluoro enol silyl ethers in almost quantitative yields. As a synthetic application of the 2,2-difluoro enol silyl ether, a novel fluorinated brassinosteroid was synthesized.
引用
收藏
页码：795 / 799
页数：5
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