REDOX ADDITION-ELIMINATION PROCESSES OF CLUSTER-BOUND LIGANDS - OXIDATIVE ELIMINATION OF CO FROM CO3(CO)9C-OH AND REDUCTIVE ADDITION OF ACETYLENE TO CO3(CO)9H

被引：22

作者：

FACHINETTI, G

PUCCI, S

ZANAZZI, PF

METHONG, U

机构：

[1] CNR,CTR STUDIO MACROMOLEC STEREORDINATE & OTTICAMENTE ATTIVE,I-56100 PISA,ITALY

[2] UNIV PERUGIA,IST MINERAL,I-06100 PERUGIA,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1002/anie.197906191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of acetylene with the hydrido cluster 1 in solution at room temperature leads immediately to the saturated compound 2. The cluster 1 was obtained from Co3(CO)9COH by oxidative elimination of CO and isolated at low temperature. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

收藏

页码：619 / 620

页数：2

相关论文

共 8 条

[1] CRYSTAL-STRUCTURE AND MOLECULAR-GEOMETRY OF HRU3(CO)10(C=NME2), INCLUDING DIRECT LOCATION OF MU-2-BRIDGING HYDRIDE LIGAND [J].

CHURCHILL, MR ;

DEBOER, BG ;

ROTELLA, FJ .

INORGANIC CHEMISTRY, 1976, 15 (08) :1843-1853

[2] METAL CLUSTERS IN CATALYSIS .10. NEW FISCHER-TROPSCH SYNTHESIS [J].

DEMITRAS, GC ;

MUETTERTIES, EL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (08) :2796-2797

[3] SYNTHESIS AND CHARACTERIZATION OF THE CLUSTER ACID CO3(CO)9C-OH - METAL-CARBONYL COMPLEX IN WHICH A CARBONYL OXYGEN-BONDED HYDROGEN IS CONVERTED INTO A METAL-BONDED HYDROGEN [J].

FACHINETTI, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (09) :397-398

[4] PHOTOINDUCED DE-CLUSTERIFICATION OF HCCO3(CO)9, CH3CCO3(CO)9, AND HFECO3(CO)12 [J].

GEOFFROY, GL ;

EPSTEIN, RA .

INORGANIC CHEMISTRY, 1977, 16 (11) :2795-2799

[5]

ORPEN AG, 1978, HYDEX PROGRAM LOCATI

[6] ORGANOCOBALT CLUSTER COMPLEXES .8. PREPARATION OF FUNCTIONAL ALKYLIDYNETRICOBALT NONACARBONYL COMPLEXES FROM DICOBALT OCTACARBONYL [J].

SEYFERTH, D ;

HALLGREN, JE ;

HUNG, PLK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 50 (01) :265-275

[7]

SHELDRICK GM, SHELX76 PROGRAM CRYS

[8] HYDROCARBON FORMATION FROM METAL-CARBONYL CLUSTERS SUPPORTED ON HIGHLY DIVIDED OXIDES [J].

SMITH, AK ;

THEOLIER, A ;

BASSET, JM ;

UGO, R ;

COMMEREUC, D ;

CHAUVIN, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) :2590-2591