RUTHENIUM(II) AND RHODIUM(I) COMPLEXES WITH SOME NITROGEN-SULFUR DONOR LIGANDS AND TRIPHENYLPHOSPHINE

被引：8
作者：
JAYAKUMAR, N [1 ]
YOGALAKSHMI, P [1 ]
NATARAJAN, K [1 ]
机构：
[1] BHARATHIAR UNIV,DEPT CHEM,COIMBATORE 641046,INDIA
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1990年 / 20卷 / 06期
关键词：
D O I：
10.1080/00945719008048163
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Several new hexa-coordinated ruthenium(II) and penta-coordinated rhodium(I) complexes of the types [RuX(CO)(LL)(PPh3)2] (X=H, Cl), [Rh(CO)(LL)(PPh3)2] and [Rh(LL)(PPh 3)3] [where LL = RHN-N=CSSR’ (R=H, R'=CH3; R=R’=COC6H5) and RR'C=NN=CSSCH3 (R=CH3, R'=C6H 5; R = R’=C6H5)] have been synthesised. S-Methyl-dithiocarbazate and S-benzoyl-β -(N-benzoyl)dithiocarbazate in alkaline medium and the Schiff bases in neutral medium deprotonate and behave as a uninegative bidentate sulphur-nitrogen (NS-) chelating ligands. All the new complexes obtained have been characterised on the basis of their analytical and spectroscopic data. © 1990, Taylor & Francis Group, LLC. All rights reserved.
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页码：661 / 671
页数：11
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