TEMPERATURE DEPENDENCE OF 4 COPOLYMERIZATION PARAMETERS OF VINYLIDENE CHLORIDE-ISOBUTYLENE COPOLYMERS

被引:1
作者
JOHNSEN, U
KOLBE, K
机构
[1] Deutschen Kunststoff- Institut, Darmstadt
来源
KOLLOID-ZEITSCHRIFT AND ZEITSCHRIFT FUR POLYMERE | 1969年 / 232卷 / 01期
关键词
D O I
10.1007/BF01500170
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The copolymerization parameters of vinylidene chloride-isobutylene-copolymers were determined by NMR for polymerization temperatures of +50°C, -10°C, -30°C considering the penultimate effect in the mechanism of copolymerization. The differences of the energies of activation and the frequency factors were derived from the temperature dependence of the copolymerization parameters. © 1969 Dr. Dietrich Steinkopff Verlag.
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页码:712 / &
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