KINETICS OF POLYMER-CHAINS IN ELONGATIONAL FLOW

被引:11
作者
DARINSKII, AA
SAPHIANNIKOVA, MG
机构
[1] Institute of Macromolecular Compounds, Russian Academy of Sciences, St Petersburg, 199004
关键词
D O I
10.1016/0022-3093(94)90601-7
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The Brownian dynamics technique was used to simulate the kinetics of neutral and charged polymer chains in elongational flow. A macromolecule is represented by a dumbbell with conformation-dependent parameters. The simulation results were compared with predictions of the Peterline-de Gennes kinetic equation. It was shown that the theory works quite well beyond the limits of 'coil-stretched chain' transition region.
引用
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页码:932 / 934
页数:3
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