EXTRACTION AND SOLUTION THERMODYNAMICS OF COMPLEXATION OF ALKALI AND ALKALINE-EARTH CATIONS BY CALIX[4]ARENE AMIDES

被引：86

作者：

ARNAUDNEU, F ^{[1
]}

BARRETT, G ^{[1
]}

FANNI, S ^{[1
]}

MARRS, D ^{[1
]}

MCGREGOR, W ^{[1
]}

MCKERVEY, MA ^{[1
]}

SCHWINGWEILL, MJ ^{[1
]}

VETROGON, V ^{[1
]}

WECHSLER, S ^{[1
]}

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1995年 / 03期

关键词：

D O I：

10.1039/p29950000453

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The extracting properties of nine new calix[4]arene tetraamides towards the entire alkali cation series and strontium have been determined. One of the amides bearing propargyl (prop-2-ynyl) residues on the nitrogen atoms has also been tested in complexation in methanol for the same cations. The enthalpies and entropies of complexation of alkali and alkaline-earth cations by the diethyl and pyrrolidinyl tetraamides in methanol and of alkali cations by the diethyl tetraamide in acetonitrile have been determined for the first time from calorimetric measurements. The data are compared with data for calixarene esters and solvent effects are discussed in the light of earlier results.

引用

页码：453 / 461

页数：9

共 22 条

[1]

ANDREETTI GD, 1990, CALIXARENES, P87

[2] THE PREPARATION AND PROPERTIES OF A NEW LIPOPHILIC SODIUM SELECTIVE ETHER ESTER LIGAND DERIVED FROM PARA-TERT-BUTYLCALIX(4)ARENE [J].

ARDUINI, A ;

POCHINI, A ;

REVERBERI, S ;

UNGARO, R ;

ANDREETTI, GD ;

UGOZZOLI, F .

TETRAHEDRON, 1986, 42 (07) :2089-2100

[3] MOLECULAR INCLUSION IN FUNCTIONALIZED MACROMOLECULES .15. PARA-TERT-BUTYLCALIX[4]ARENE TETRA-ACETAMIDE - A NEW STRONG RECEPTOR FOR ALKALI CATIONS [J].

ARDUINI, A ;

GHIDINI, E ;

POCHINI, A ;

UNGARO, R ;

ANDREETTI, GD ;

CALESTANI, G ;

UGOZZOLI, F .

JOURNAL OF INCLUSION PHENOMENA, 1988, 6 (02) :119-134

[4]

ARNAUDNEU F, 1991, NEW J CHEM, V15, P33

[5] SYNTHESIS, X-RAY CRYSTAL-STRUCTURES, AND CATION-BINDING PROPERTIES OF ALKYL CALIXARYL ESTERS AND KETONES, A NEW FAMILY OF MACROCYCLIC MOLECULAR RECEPTORS [J].

ARNAUDNEU, F ;

COLLINS, EM ;

DEASY, M ;

FERGUSON, G ;

HARRIS, SJ ;

KAITNER, B ;

LOUGH, AJ ;

MCKERVEY, MA ;

MARQUES, E ;

RUHL, BL ;

SCHWINGWEILL, MJ ;

SEWARD, EM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) :8681-8691

[6] CATION COMPLEXATION BY CHEMICALLY-MODIFIED CALIXARENES .7. TRANSPORT OF ALKALI CATIONS BY P-TERT-BUTYLCALIX[N]ARENE ESTERS AND AMIDES [J].

ARNAUDNEU, F ;

FANNI, S ;

GUERRA, L ;

MCGREGOR, W ;

ZIAT, K ;

SCHWINGWEILL, MJ ;

BARRETT, G ;

MCKERVEY, MA ;

MARRS, D ;

SEWARD, EM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (01) :113-118

[7] SELECTIVE ALKALI-METAL CATION COMPLEXATION BY CHEMICALLY MODIFIED CALIXARENES .4. EFFECT OF SUBSTITUENT VARIATION ON THE NA+/K+ SELECTIVITY IN THE ESTER SERIES AND X-RAY CRYSTAL-STRUCTURE OF THE TRIFLUOROETHYL ESTER [J].

ARNAUDNEU, F ;

BARRETT, G ;

CREMIN, S ;

DEASY, M ;

FERGUSON, G ;

HARRIS, SJ ;

LOUGH, AJ ;

GUERRA, L ;

MCKERVEY, MA ;

SCHWINGWEILL, MJ ;

SCHWINTE, P .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1992, (07) :1119-1125

[8]

Burgess J., 1978, METAL IONS SOLUTION

[9] NEW METAL CATION-SELECTIVE IONOPHORES DERIVED FROM CALIXARENES - THEIR SYNTHESES AND ION-BINDING PROPERTIES [J].

CHANG, SK ;

CHO, I .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (02) :211-214

[10] THE SOLUTION THERMODYNAMICS OF ETHYL PARA-TERT-BUTYLCALIX[4]ARENE TETRAACETATE AND ITS ALKALI-METAL COMPLEXES IN ACETONITRILE AND METHANOL [J].

DENAMOR, AFD ;

DESUEROS, NA ;

MCKERVEY, MA ;

BARRETT, G ;

NEU, FA ;

SCHWINGWEILL, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (21) :1546-1548

← 1 2 3 →