ASYMMETRIC-SYNTHESIS OF SYN 1,2-DIOLS VIA THE REACTION OF ALDEHYDES WITH CHIRAL GAMMA-(TETRAHYDROPYRANYLOXY)ALLYLSTANNANES

被引：28
|
作者：
YAMAMOTO, Y
KOBAYASHI, K
OKANO, H
KADOTA, I
机构：
[1] Department of Chemistry, Faculty of Science, Tohoku University
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 26期
关键词：
D O I：
10.1021/jo00052a002
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Asymmetric synthesis of syn 1,2-diols 3 has been accomplished via the reaction of the chiral gamma-alkoxy-substituted allylstannane 1 with aldehydes in the presence of AlCl3 or AlCl3.OEt2, followed by a five-step operation to remove the chiral auxiliary.
引用
收藏
页码：7003 / 7005
页数：3
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