CALCULATION OF ACTIVATION-ENERGY AND PREEXPONENTIAL FACTORS FROM RISING TEMPERATURE DATA AND THE GENERATION OF TG AND DTG CURVES FROM A-VALUES AND E-VALUES

被引：45

作者：

DOLLIMORE, D

EVANS, TA

LEE, YF

WILBURN, FW

机构：

[1] Department of Chemistry, University of Toledo, Toledo

来源：

THERMOCHIMICA ACTA | 1991年 / 188卷 / 01期

关键词：

D O I：

10.1016/0040-6031(91)80206-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

After reviewing present methods of evaluating E, the activation energy, and A, the pre-exponential constant, and pointing out some of the inherent weaknesses of the method, a technique is outlined whereby a DTG and/or TG curve may be produced for direct comparison with experimental curves by assuming values for A and E and using finite difference techniques to produce such a curve.

引用

页码：77 / 85

页数：9

共 6 条

[1]

Brown M.E., 1988, INTRO THERMAL ANAL

[2]

CRIADO M, 1988, THERMOCHIM ACTA, V147, P377

[3] COMPARISON OF EXPERIMENTAL KINETIC DECOMPOSITION DATA WITH MASTER DATA USING A LINEAR PLOT METHOD [J].