THEORETICAL CONSIDERATIONS ON THE OXIDATION OF PROPYLENE ON TRANSITION-METAL MOLYBDATES

被引：4

作者：

VISWANATHAN, B ^{[1
]}

BHUVANA, CV ^{[1
]}

SASTRI, MVC ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,MAT SCI RES INST,MADRAS 600036,INDIA

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1979年 / 11卷 / 02期

关键词：

D O I：

10.1007/BF02074208

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular orbital calculations of charge distributions for the π-allyl complex with transition metal ions in molybdates show that the activated π-allyl species is formed by transfer of charge density to the metal ion. The relative charge distributions on the three carbon atoms of the adsorbed allyl species govern the course of oxidation reaction. © 1979 Akadémiai Kiadó.

引用

页码：173 / 177

页数：5

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