PREDICTION OF THERMODYNAMIC PROPERTIES OF POLAR MIXTURES BY A GROUP SOLUTION MODEL

被引:99
作者
RATCLIFF, GA
CHAO, KC
机构
[1] Chevron Research Company, Richmond, California
[2] Mcgill University, Montreal, Quebec
[3] Oklahoma State University, Stillwater, Oklahoma
关键词
D O I
10.1002/cjce.5450470208
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A modified group solution model for liquid mixtures is presented. The model differs from previous models in that the Bronsted‐Koefoed congruence principle is used to describe the effect of molecular size. The model has been tested for mixtures involving paraffin hydrocarbons, alcohols and water at low pressures. Such systems involve binary mixtures of the groups methylene and hydroxyl, and are reasonably represented by the model. Data presented enable the approximate equilibrium properties of such solutions at low pressures to be predicted at 40°C and 90°C. Interpolation and reasonable extrapolation from these temperatures should be satisfactory. Copyright © 1969 Canadian Society for Chemical Engineering
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页码:148 / &
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