A LOW-CHLORIDE CALOMEL REFERENCE ELECTRODE OF LOW POLARIZABILITY IN ACETONITRILE

被引：19
作者：
BRAVO, O
IWAMOTO, RT
机构：
[1] Department of Chemistry, University of Kansas, Lawrence, KS
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1969年 / 23卷 / 03期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0368-1874(69)80030-4
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The characteristics of a mercury, mercury(I) chloride electrode in acetonitrile containing potassium chloride and potassium perchlorate and 0.10 F in Et4NClO4 have been examined. The electrode has been found to be reproducible, stable, unaltered by small amounts of water, and suitable for conventional polarographic work when the current density at the mercury pool is less that 2.0 μA cm-2. © 1969.
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页码：419 / &
相关论文
共 16 条
[1]  
COETZEE JF, 1965, J AM CHEM SOC, V87, P2629
[2]  
COULTER PDT, 1965, THESIS U KANSAS
[3]  
CRUSE V, 1951, Z ELEKTROCHEM, V55, P405
[4]  
DAVIES CW, 1962, ION ASSOCIATION, P96
[5]  
Henderson P, 1907, Z PHYS CHEM-STOCH VE, V59, P118
[6]  
Ives D. J., 1961, REFERENCE ELECTRODES
[7]   THE SILVER-SILVER HALIDE ELECTRODES - PREPARATION, STABILITY, REPRODUCIBILITY, AND STANDARD POTENTIALS IN AQUEOUS AND NON-AQUEOUS MEDIA [J].
JANZ, GJ ;
TANIGUCHI, H .
CHEMICAL REVIEWS, 1953, 53 (03) :397-437
[8]   CONDUCTANCE AND ASSOCIATION BEHAVIOR OF ALKALI METAL PERCHLORATES AND TETRAPHENYLBORIDES IN ANHYDROUS ACETONITRILE [J].
KAY, RL ;
HALES, BJ ;
CUNNINGH.GP .
JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (12) :3925-&
[9]   CONTROLLED-POTENTIAL AND DERIVATIVE POLAROGRAPH [J].
KELLEY, MT ;
JONES, HC ;
FISHER, DJ .
ANALYTICAL CHEMISTRY, 1959, 31 (09) :1475-1485
[10]   CONTROLLED-POTENTIAL POLAROGRAPHIC POLARIZING UNIT WITH ELECTRONIC SCAN AND LINEAR RESIDUAL CURRENT COMPENSATION [J].
KELLEY, MT ;
FISHER, DJ ;
JONES, HC .
ANALYTICAL CHEMISTRY, 1960, 32 (10) :1262-1265
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