QUANTUM YIELD OF PHOTONITROSATION OF CYCLOHEXANE IN HOMOGENEOUS SYSTEM

被引：10

作者：

MIYAMA, H

FUKUZAWA, K

HARUMIYA, N

ITO, Y

WAKAMATS.S

机构：

[1] Basic Research Laboratory, Toyo Rayon Co., Ltd., Tebiro, Kamakura

[2] Nagoya Laboratory, Toyo Rayon Co., Ltd., Minato-ku, Nagoya

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 12期

关键词：

D O I：

10.1021/j100846a053

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Quantum yield of photonitrosation of cyclohexane was measured in a homogeneous system, where the oxime hydrochloride formed was dissolved by adding chloroform to the reaction mixture. Obtained values were 0.80 ± 0.06 at 365 mμ, 0.79 ± 0.06 at 436 mμ, and 0.97 ± 0.13 at 578 mμ. These results were discussed from the mechanistic viewpoint.

引用

页码：4345 / &

共 7 条

[1] QUANTUM YIELD OF PHOTONITROSATION OF CYCLOHEXANE UNDER A FLASH LAMP [J].