SYNTHESIS OF BINUCLEAR COPPER(II) COMPLEXES WITH EXPANDED PORPHYRINS

被引：0

作者：

AMANI, S

SESSLER, J

机构：

[1] UNIV ARAK,DEPT CHEM,ARAK,IRAN

[2] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION | 1994年 / 13卷 / 02期

关键词：

COPPER(II); EXPANDED PORPHYRINS; COMPLEXES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of some new binuclear copper(II) complexes, based on the use of large, pyrole- containing macrocycles, the so called ''expanded porphyrins'', [Cu-2(macrycycle)](+4) is described. Electron Spin Resonance (ESR) studies indicate a weak ''half-field line'' which is characteristic of the Cu(II)-Cu(II) dimer, is observed at about 1600G. The observation of this band strongly suggests that the hyperfine structure arises from a spin triplet species.

引用

页码：83 / 90

页数：8

共 57 条

[1]

ALGRA HA, 1977, PHYSICA, V926, P187

[2]

APTSHYLER SA, 1975, J PHYS C SOLID STATE, V8, P1907

[3] PREPARATION, CRYSTAL AND MOLECULAR-STRUCTURE OF AQUADICHLOROCAFFEINECOPPER(II) [J].