SOLVENT CONTROL OF STRUCTURAL TYPE - 3 DIFFERENT STRUCTURES FROM THE REACTION OF A DIMERIC COPPER COMPLEX WITH LANTHANUM NITRATE IN 3 DIFFERENT SOLVENTS

被引：21

作者：

BLAKE, AJ ^{[1
]}

MILNE, PEY ^{[1
]}

WINPENNY, REP ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 24期

关键词：

D O I：

10.1039/dt9930003727

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of a dimeric copper complex, [Cu2L4] 1 (L = C5H3ClNO-, the anion of 6-chloro-2-hydroxypyridine), with hydrated lanthanum nitrate has been studied. The crystalline products are determined by the solvent used. If the reaction is carried out in a mixture of methanol-dichloromethane a compound of stoichiometry [Cu3LaL5(NO3)3(OMe)(MeOH)2].1.5MeOH.0.5Et2O 2 is isolated. If the reaction is carried out in ethanol-dichloromethane a compound of stoichiometry [Cu3LaL8(NO3)(EtOH)].0.5Et2O 3 is found. If acetonitrile-dichloromethane is used the complex [Cu2La2L8(HL)2(NO3)2]-2HL.2MeCN 4 can be crystallised. All of these compounds have been characterised by X-ray crystallography and the unusual structures are described.

引用

页码：3727 / 3734

页数：8

共 26 条

[1] ISOLATION AND CRYSTAL-STRUCTURE OF THE CUBANE-LIKE CLUSTER [CR4(OH)4(MHP)8] (MHP=6-METHYL-2-HYDROXYPYRIDINATE) [J].

AKHTER, L ;

CLEGG, W ;

COLLISON, D ;

GARNER, CD .

INORGANIC CHEMISTRY, 1985, 24 (11) :1725-1728

[2] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [LN2CU4] HEXANUCLEAR CLUSTERS (WHERE LN = TRIVALENT LANTHANIDE) - MECHANISM OF THE GD(III)-CU(II) MAGNETIC INTERACTION [J].

ANDRUH, M ;

RAMADE, I ;

CODJOVI, E ;

GUILLOU, O ;

KAHN, O ;

TROMBE, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) :1822-1829

[3] CRYSTAL AND MOLECULAR-STRUCTURE OF AND MAGNETIC COUPLING IN 2 COMPLEXES CONTAINING GADOLINIUM(III) AND COPPER(II) IONS [J].

BENCINI, A ;

BENELLI, C ;

CANESCHI, A ;

CARLIN, RL ;

DEI, A ;

GATTESCHI, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :8128-8136

[4] CRYSTAL AND MOLECULAR-STRUCTURE AND MAGNETIC-PROPERTIES OF A TRINUCLEAR COMPLEX CONTAINING EXCHANGE-COUPLED GDCU2 SPECIES [J].

BENCINI, A ;

BENELLI, C ;

CANESCHI, A ;

DEI, A ;

GATTESCHI, D .

INORGANIC CHEMISTRY, 1986, 25 (04) :572-575

[5]

BENELLI C, 1990, INORG CHEM, V29, P1751

[6]

BENELLI C, UNPUB

[7] CRYSTAL-STRUCTURE AND UV PHOTOELECTRON-SPECTRA OF TETRAKIS-(6-METHYL-2-OXOPYRIDINATO)DIRHODIUM [J].

BERRY, M ;

GARNER, CD ;

HILLIER, IH ;

MACDOWELL, AA ;

CLEGG, W .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (11) :494-495

[8] PREPARATION AND CRYSTAL-STRUCTURE OF TETRACOPPER(I) TETRAKIS(6-METHYL-2-OXYPYRIDINE), [CU4(MHP)4] [J].

BERRY, M ;

CLEGG, W ;

GARNER, CD ;

HILLIER, IH .

INORGANIC CHEMISTRY, 1982, 21 (04) :1342-1345

[9] NEW ROUTES TO COPPER-LANTHANOID COMPLEXES .1. VIA A METALLOMACROCYCLE [J].

BLAKE, AJ ;

GOULD, RO ;

MILNE, PEY ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (20) :1453-1455

[10] NEW ROUTES TO COPPER-LANTHANOID COMPLEXES - VIA A METAL DIMER [J].

BLAKE, AJ ;

GOULD, RO ;

MILNE, PEY ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (06) :522-524

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