N-TERT-BUTOXYCARBONYL-2-(TERT-BUTYLDIMETHYLSILOXY)PYRROLE AS A GLYCINE ANION EQUIVALENT - A FLEXIBLE ENANTIOSELECTIVE ACCESS TO POLYHYDROXY-ALPHA-AMINO ACIDS

被引：22

作者：

CASIRAGHI, G ^{[1
]}

RASSU, G ^{[1
]}

SPANU, P ^{[1
]}

PINNA, L ^{[1
]}

机构：

[1] CNR,IST APPLICAZ TECN CHIM AVANZATE,I-07100 SASSARI,ITALY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 15期

关键词：

D O I：

10.1016/0040-4039(94)85236-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient stereoselective route to polyhydroxy-alpha-amino acids 7a-f was developed by exploiting N-tert-butoxycarbonyl-2-(tert-butyldimethylsiloxy)pyrrole as a glycine anion equivalent.

引用

页码：2423 / 2426

页数：4

共 4 条

[1] GENERAL-APPROACH TO HYDROXYLATED ALPHA-AMINO-ACIDS EXPLOITING N-(TERT-BUTOXYCARBONYL)-2-(TERT-BUTYLDIMETHYLSILOXY)PYRROLE
RASSU, G
ZANARDI, F
CORNIA, M
CASIRAGHI, G
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (17): : 2431 - 2437
[2] N-(TERT-BUTOXYCARBONYL)-2-(TERT-BUTYLDIMETHYLSILOXY)PYRROLE - A PROMISING COMPOUND FOR SYNTHESIS OF CHIRAL NONRACEMIC HYDROXYLATED PYRROLIDINE DERIVATIVES
CASIRAGHI, G
RASSU, G
SPANU, P
PINNA, L
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (14): : 3760 - 3763
[3] SELECTIVE REACTIONS USING N-(TERT-BUTOXYCARBONYL)-2-(TERT-BUTYLDIMETHYLSILOXY)PYRROLE - CONCISE ASYMMETRIC SYNTHESES OF (+)-1-DEOXY-8-EPI-CASTANOSPERMINE AND ITS ENANTIOMER
CASIRAGHI, G
ULGHERI, F
SPANU, P
RASSU, G
PINNA, L
FAVA, GG
FERRARI, MB
PELOSI, G
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (23): : 2991 - 2997
[4] Discussion Addendum For: Efficient Asymmetric Synthesis of N-tert-Butoxycarbonyl alpha-Amino Acids using 4-tert-Butoxycarbonyl-5,6Diphenylmorpholin-2- one: (R)-(N-tert-Butoxycarbonyl) allylglycine (4-Pentenoic acid, 2[[(1,1-Dimethylethoxy)carbonyl]amino]-, (2R)-)
Looper, Ryan E.
Williams, Robert M.
ORGANIC SYNTHESES, 2012, 89 : 394 - 403

← 1 →