SYNTHESIS AND CHARACTERIZATION OF A THERMALLY ROBUST TITANIUM DINITROGEN COMPLEX - THE CRYSTAL-STRUCTURE OF [([(ME3SI)2N]TICL(PYRIDINE)2)2(MU-ETA-ETA'-N2)]

被引：39

作者：

BEYDOUN, N ^{[1
]}

DUCHATEAU, R ^{[1
]}

GAMBAROTTA, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000244

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of trans-[TiCl2(tmeda)2] (tmeda = N, N, N', N'-tetramethylethylenediamine) with one equivalent of LiN(Me3Si)2, followed by treatment with pyridine, led to the formation of a novel Ti-dinitrogen complex [{TiCl[N(SiMe3)2](pyridine)2}(pyridine)2}2(mu-eta:eta'-N2)].

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页码：244 / 246

页数：3

相关论文

共 34 条

[1] ACETYLENE DERIVATIVES OF TITANOCENE [J].

ALT, HG ;

ENGELHARDT, HE ;

RAUSCH, MD ;

KOOL, LB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) :3717-3718

[2] TITANOCENE AS AN INTERMEDIATE IN REACTIONS INVOLVING MOLECULAR-HYDROGEN AND NITROGEN [J].

BERCAW, JE ;

BELL, LG ;

BRINTZIN.HH ;

MARVICH, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (04) :1219-&

[3] MOLECULAR-STRUCTURE OF (CP2TI(PME3))2(MU-N2), A TITANOCENE DINITROGEN COMPLEX [J].

BERRY, DH ;

PROCOPIO, LJ ;

CARROLL, PJ .

ORGANOMETALLICS, 1988, 7 (02) :570-572

[4] TITANIUM HEXACARBONYL, TI(CO)6, AND TITANIUM HEXADINITROGEN, TI(N2)6 .1. SYNTHESIS USING TITANIUM ATOMS AND CHARACTERIZATION BY MATRIX IR AND ULTRAVIOLET-VISIBLE SPECTROSCOPY [J].

BUSBY, R ;

KLOTZBUCHER, W ;

OZIN, GA .

INORGANIC CHEMISTRY, 1977, 16 (04) :822-828

[5] TITANACYCLES DERIVED FROM REDUCTIVE COUPLING OF NITRILES, ALKYNES, ACETALDEHYDE, AND CARBON-DIOXIDE WITH BIS(PENTAMETHYLCYCLOPENTADIENYL)(ETHYLENE)TITANIUM(II) [J].

COHEN, SA ;

BERCAW, JE .

ORGANOMETALLICS, 1985, 4 (06) :1006-1014

[6] STRUCTURE AND REACTIVITY OF BIS(PENTAMETHYLCYCLOPENTADIENYL)(ETHYLENE)TITANIUM(II), A SIMPLE OLEFIN ADDUCT OF TITANIUM [J].

COHEN, SA ;

AUBURN, PR ;

BERCAW, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (05) :1136-1143

[7]

Demerseman B., 1985, J ORGANOMET CHEM, V297, pC35

[8] CARBON-CARBON DOUBLE-BOND FORMATION IN THE INTERMOLECULAR ACETONITRILE REDUCTIVE COUPLING PROMOTED BY A MONONUCLEAR TITANIUM(II) COMPOUND - PREPARATION AND CHARACTERIZATION OF 2 TITANIUM(IV) IMIDO DERIVATIVES [J].

DUCHATEAU, R ;

WILLIAMS, AJ ;

GAMBAROTTA, S ;

CHIANG, MY .

INORGANIC CHEMISTRY, 1991, 30 (25) :4863-4866

[9] FORMATION AND CHARACTERIZATION OF ETA-2-IMINE AND ETA-2-AZOBENZENE DERIVATIVES OF TITANIUM CONTAINING ANCILLARY ARYLOXIDE LIGATION [J].

DURFEE, LD ;

HILL, JE ;

FANWICK, PE ;

ROTHWELL, IP .

ORGANOMETALLICS, 1990, 9 (01) :75-80

[10] REDUCTIVE ELIMINATION PATHWAYS TO LOW-VALENT TITANIUM ARYLOXIDE COMPLEXES [J].

DURFEE, LD ;

FANWICK, PE ;

ROTHWELL, IP ;

FOLTING, K ;

HUFFMAN, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (15) :4720-4722

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